Counter anion dependent gradual spin transition in a 1D cobalt(ii) coordination polymer.
نویسندگان
چکیده
One Co(ii) SCO coordination polymer [Co(enbzpy)(μ1,5-dca)]n(PF6)n (·PF6) has been isolated and characterised structurally and magnetostructurally. The properties of ·PF6 are compared with the reported perchlorate analogue [Co(enbzpy)(μ1,5-dca)]n(ClO4)n (·ClO4). The gradual spin transition in ·PF6 in contrast to an abrupt spin transition with a hysteresis loop in ·ClO4 has been analysed in terms of structural factors.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 44 17 شماره
صفحات -
تاریخ انتشار 2015